Charlton will be making their first ever trip to The Keepmoat stadium on Tuesday night and only their second ever visit to Doncaster.
Rovers will be hoping to bounce back from Saturdays defeat against Birmingham.
Rovers bossed the majority of the game but came away pointless after Jerome Cameron scored in the first minute of the second half to give the blues a 1-0 victory
Charlton last time out suffered a 3-1 home defeat against Wolverhampton Wanderers.
Rovers home form so far has seen them draw with Cardiff City 1-1, they followed that up with a 1-0 victory over Coventry City.
Charlton have yet to pick up a point on their travels after losing 1-0 at Watford and 2-1 against Preston.
In their last six home games Doncaster have won 4, drawn 1 and lost 1.
Charlton`s away form has been poor winning 1 and losing 5 in their last six.
Rovers are currently 14th in the table, one point and two places above Charlton.
It will be the first time the clubs have met since 1957 when the two clubs met at The Valley on Christmas Day and the return at Belle Vue was on Boxing Day. The clubs have only ever met on four occasions with Doncaster winning 1 and Charlton 3.
1935/36 Doncaster Rovers 2-0 Charlton Athletic
1935/36 Charlton Athletic 3-0 Doncaster Rovers
1957/58 Charlton Athletic 2-0 Doncaster Rovers
1957/58 Doncaster Rovers 1-2 Charlton Athletic
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